Players Wearing #66
| Player | Team | Date(s) Worn |
|---|---|---|
| Mario Lemieux | NHL All-Star Team | February 9, 1988 |
| Mario Lemieux | NHL All-Star Team | February 7, 1989 |
| Mario Lemieux | NHL All-Star Team | January 21, 1990 |
| Mario Lemieux | NHL All-Star Team | January 18, 1992 |
| Mario Lemieux | NHL All-Star Team | January 20, 1996 |
| Mario Lemieux | NHL All-Star Team | January 18, 1997 |
| Mario Lemieux | NHL All-Star Team | February 4, 2001 |
| Mario Lemieux | NHL All-Star Team | February 2, 2002 |
| Mario Lemieux | Pittsburgh Penguins | 1984 - 1994 |
| Mario Lemieux | Pittsburgh Penguins | 1995 - 1997 |
| Mario Lemieux | Pittsburgh Penguins | 2000 - 2006 |
| Gino Odjick | Vancouver Canucks | 1990 - 1991 |
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