Players Wearing #4
| Player | Team | Date(s) Worn |
|---|---|---|
| Reg Abbott | Montreal Canadiens | 1952 - 1953 |
| Sid Abel | Detroit Red Wings | 1939 - 1940 |
| Bruce Affleck | St. Louis Blues | 1974 - 1979 |
| Greg Andrusak | Pittsburgh Penguins | 1993 - 1994 |
| Bob Armstrong | Boston Bruins | 1950 - 1951 |
| Bob Armstrong | Boston Bruins | 1952 - 1962 |
| Fred Arthur | Hartford Whalers | 1980 - 1981 |
| Reid Bailey | Toronto Maple Leafs | 1982 - 1983 |
| Nolan Baumgartner | Dallas Stars | 2006 - 2007 |
| Nolan Baumgartner | Vancouver Canucks | 2002 - 2006 |
| Bob Baun | Detroit Red Wings | 1968 - 1971 |
| Paul Baxter | Pittsburgh Penguins | 1980 - 1983 |
| Paul Baxter | Quebec Nordiques | 1979 - 1980 |
| Jean Beliveau | Montreal Canadiens | 1953 - 1971 |
| Shawn Belle | Minnesota Wild | 2006 - 2007 |
| Bryan Berard | Chicago Blackhawks | 2003 - 2004 |
| Bryan Berard | Columbus Blue Jackets | 2005 - 2007 |
| Bryan Berard | New York Islanders | 2007 - present |
| Bill Berg | New York Islanders | 1990 - 1991 |
| Marc Bergevin | St. Louis Blues | 1996 - 2000 |
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